372 lines
9.9 KiB
Nix
372 lines
9.9 KiB
Nix
{ chemistry, ... }:
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let
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inherit(chemistry) compound;
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in
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{
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"2-octyldodecyl" = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "2-Octyl||dodecyl||gruppe"}";
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};
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};
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description = {
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deu = ''
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eine Alkyl\-gruppe
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'';
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};
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data = {
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kind = "Chemical";
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short = "2-OD";
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struct = ''
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\cheme{\chemfig{-[:90]-[::60]-[::-60]-[::60]-[::-60]-[::60]-[::-60]-[::60]-[::-60]-[::60](-[::60]-[::60]-[::60]-[::-60]-[::60]-[::-60]-[::60]-[::-60])-[::-60]-[::60]R}}{}
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'';
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};
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};
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acetyl = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "Acetyl||gruppe"}";
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};
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};
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description = {
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deu = ''
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\ch{H3CCO},
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eine Acyl\-gruppe
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'';
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};
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data = {
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kind = "Chemical";
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short = "Ac";
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struct = ''
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\cheme{\chemfig{R-[:30](=[::60]O)-[::-60]CH_3}}{}
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'';
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};
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};
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benzyl = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "Benzyl||gruppe"}";
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};
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};
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description = {
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deu = ''
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\ch{-CH2<phenyl>},
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eine Aryl\-gruppe
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'';
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};
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data = {
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kind = "Chemical";
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short = "Bzl";
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struct = ''
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\cheme{\chemfig{R-[:30]-[::-60]*6(-=-=-=)}}{}
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'';
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};
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};
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cyclopentadienyl = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "Cyclo||pentadienyl||gruppe"}";
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};
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};
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description = {
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deu = ''
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vom ${compound.format "Cyclo|penta|di|en"}\-anion (\ch{C5H5-}) abgeleitet,
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eine Aryl\-gruppe
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'';
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};
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data = {
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kind = "Chemical";
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short = "Cp";
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struct = ''
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\cheme{\chemfig{R-[:30]**5(--(-[::126,0.88,,,,draw=none]\text{\ominus})---)}}{}
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'';
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};
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};
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"cyclopentadienyl*" = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "Tetra|methyl||cyclo||penta|di|enyl||gruppe"}";
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};
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};
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description = {
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deu = ''
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vom ${compound.format "Penta|methyl||cyclo|penta|di|en"}\-anion (\ch{C5(CH3)5-}) abgeleitet,
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eine Aryl\-gruppe
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'';
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};
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data = {
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kind = "Chemical";
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short = "<cyclopentadienyl>*";
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};
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};
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dipp = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "Di|iso|propyl||phenyl||gruppe"}";
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};
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};
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description = {
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deu = ''
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\ch{-<phenyl>(<isoPropyl>)2},
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eine Aryl\-gruppe
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'';
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};
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data = {
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kind = "Chemical";
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short = "'dipp'";
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};
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};
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ethyl = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "Ethyl||gruppe"}";
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};
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};
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description = {
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deu = ''
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\ch{-CH2CH3}, eine Alkyl\-gruppe
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'';
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};
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data = {
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kind = "Chemical";
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short = "Et";
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struct = ''
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\cheme{\chemfig{R-[:30]-[:-30]CH_3}}{}
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'';
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};
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};
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ferrocenyl = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "Ferrocenyl||gruppe"}";
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};
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};
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description = {
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deu = ''
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von ${compound.format "Ferrocen"} (\ch{Fe(h5 -C5H5)2}) abgeleitet, eine Metallocyl\-gruppe
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'';
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};
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data = {
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kind = "Chemical";
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short = "Fc";
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struct = ''
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\cheme{\chemname{\chemfig{-[:-303.51,0.4476]-[::303.51,,,,]-[::303.51,0.4476]<[::251.67,0.7741]@{r5}{}>[::329.64,0.7741]-[::205.18,0.7472,,,draw=none]@{r1}{}-[::80,0.70]Fe-[::0,0.85]\ -[::0,0]@{r2}{}-[::85,0.7472,,,draw=none]<[::128.51,0.4476]@{r3}{}-[::56.49,,,,line width=2pt]@{r4}{}(-[::333.245]R)>[::56.49,0.4476]-[::108.33,0.7741]-[::30.36,0.7741]}}{gestaffelt}\chemname{\chemfig{<[:303.51-\rotate,0.4476]@{r15}{}-[:: 56.49,,,,line width=2pt]@{r16}{}>[:: 56.49,0.4476]-[::108.33,0.7741]-[::30.36,0.7741]-[::159.82,0.7472,,,draw=none]@{r11}{}-[::95,0.70]Fe-[:: 0,0.85]\ -[::0,0]@{r12}{}-[::85,0.7472,,,draw=none]<[::128.51,0.4476]@{r13}{}-[:: 56.49,,,,line width=2pt]@{r14}{}(-[::333.245]R)>[:: 56.49,0.4476]-[::108.33,0.7741]-[::30.36,0.7741]}}{ekliptisch}}{\draw[rotate=\rotate] (r1) ellipse (6pt and 2pt);\draw[rotate=\rotate] (r2) ellipse (6pt and 2pt);\draw[-,rotate=\rotate,line width=0.6pt] (r2)\fill[rotate=\rotate] (r3) ellipse (1.3pt and 1pt);\fill[rotate=\rotate] (r4) ellipse (1.3pt and 1pt);\fill[rotate=\rotate] (r5) ellipse (1pt and 1.3pt);\draw[rotate=\rotate] (r11) ellipse (6pt and 2pt);\draw[rotate=\rotate] (r12) ellipse (6pt and 2pt);\draw[-,rotate=\rotate,line width=0.6pt] (r12)\fill[rotate=\rotate] (r13) ellipse (1.3pt and 1pt);\fill[rotate=\rotate] (r14) ellipse (1.3pt and 1pt);\fill[rotate=\rotate] (r15) ellipse (1.3pt and 1pt);\fill[rotate=\rotate] (r16) ellipse (1.3pt and 1pt);}
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'';
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};
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};
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fmoc = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "Fluorenyl||methoxy||carbonyl||gruppe"}";
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};
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};
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description = {
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deu = ''
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\ch{???},
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Schutz\-gruppe für \acrshort{forExample} ${compound.format "Amine"}
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'';
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};
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data = {
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kind = "Chemical";
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short = "Fmoc";
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};
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};
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isoPropyl = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "Iso|propyl||gruppe"}";
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};
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};
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description = {
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deu = ''
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\ch{-CH(CH3)2},
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eine Alkyl\-gruppe
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'';
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};
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data = {
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kind = "Chemical";
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short = "^iPr";
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struct = ''
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\cheme{\chemfig{R-[:30](-[:30]CH_3)-[:-30]CH_3}}{}
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'';
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};
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};
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mesyl = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "Mesyl||gruppe"}";
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};
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};
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description = {
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deu = ''
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\ch{-SO2CH3},
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systematisch nach \acrshort{iupac}: ${compound.format "Methan||sulfonyl||gruppe"},
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die Ester und Salze der ${compound.format "Methan||sulfonsäure"} (\ch{MsOH}) werden als ${compound.format "Mesylate"} bezeichnet,
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welche als Abgangs\-gruppe für nukleo\-phile Substitutions\-reaktionen
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durch Reaktion des ${compound.format "Säure\-chlorides"} mit einem ${compound.format "Alkohol"}
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gebildet werden kann
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'';
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};
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data = {
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kind = "Chemical";
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short = "Ms";
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struct = ''
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\cheme{\chemfig{R-[:30]-S(=[::75]O)(=[::45]O)[::-60]CH_3}}{}
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'';
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};
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};
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methyl = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "Methyl||gruppe"}";
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};
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};
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description = {
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deu = ''
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\ch{-CH3}, eine Alkyl\-gruppe
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'';
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};
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data = {
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kind = "Chemical";
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short = "Me";
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struct = ''
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\cheme{\chemfig{R-[:30]CH_3}}{}
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'';
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};
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};
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naphthalenediimide = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "Naphthalen§-1,4,5,8-tetra|carboxyl§||di|imid"}";
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};
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};
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description = {
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deu = ''
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von ${compound.format "Naphthalen"} abgeleite, tetrazyklische hetero\-aromatische Gruppe
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'';
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};
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data = {
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kind = "Chemical";
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short = "NDI";
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struct = ''
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\cheme{\chemfig{*6(-(*6(-(=O)-N(-R)-(=O)-))=(*6(-=-=(*6(-(=O)-N(-R)-(=O)-))-))-=-=)}}{}
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'';
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};
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};
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phenyl = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "Phenyl||gruppe"}";
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};
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};
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description = {
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deu = ''
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von ${compound.format "Benzen"} (\ch{C6H6}) abgeleitet,
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einem aromatischen ${compound.format "Kohlen||wasserstoff"}.
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'';
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};
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data = {
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kind = "Chemical";
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short = "Ph";
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struct = ''
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\cheme{\chemfig{R-[:30]*6(-=-=-=)}}{}
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'';
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};
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};
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pyrenyl = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "Pyrenyl||gruppe"}";
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};
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};
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description = {
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deu = ''
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von ${compound.format "Pyren"} (\ch{C16H10}) abgeleitet,
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einem poly\-zyklischen aromatischen ${compound.format "Kohlen||wasserstoff"}.
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'';
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};
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data = {
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kind = "Chemical";
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short = "Py";
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};
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};
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tosyl = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "Tosyl||gruppe"}";
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};
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};
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description = {
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deu = ''
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\ch{-SO2<phenyl><methyl>},
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systematisch nach \acrshort{iupac}: ${compound.format "p-Toluen||sulfonyl||gruppe"},
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die Ester und Salze der ${compound.format "p-Toluen||sulfonsäure"} (\ch{TsOH}) werden als ${compound.format "Tosylate"} bezeichnet,
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welche als Abgangs\-gruppe für nukleo\-phile Substitutions\-reaktionen
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durch Reaktion des ${compound.format "Säure\-chlorides"} mit einem ${compound.format "Alkohol"}
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gebildet werden kann
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'';
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};
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data = {
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kind = "Chemical";
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short = "Ts";
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};
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};
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triflyl = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "Triflyl||gruppe"}";
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};
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};
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description = {
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deu = ''
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\ch{-SO2CF3},
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systematisch nach \acrshort{iupac}: ${compound.format "Tri|fluor||methan||sulfonyl||gruppe"},
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die Ester und Salze der ${compound.format "Tri|fluor||methan||sulfonsäure"} (\ch{TfOH}) werden als ${compound.format "Triflate"} bezeichnet,
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welche als Abgangs\-gruppe für nukleo\-phile Substitutions\-reaktionen
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durch Reaktion des ${compound.format "Säure\-chlorides"} mit einem ${compound.format "Alkohol"}
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gebildet werden kann
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'';
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};
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data = {
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kind = "Chemical";
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short = "Tf";
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};
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};
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trimethylsilyl = {
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section = "Substances";
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text = {
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deu = {
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tex = "${compound.format "Tri|methyl||silyl||gruppe"}";
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};
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};
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description = {
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deu = ''
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\ch{-Si(CH3)3}
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'';
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};
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data = {
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kind = "Chemical";
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short = "TMS";
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struct = ''
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\cheme{\chemfig{R-Si(-[::-120]H_3C)(-[::120]H_3C)-[::0]CH_3}}{}
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'';
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};
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};
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} |