{ chemistry, ... }: let inherit(chemistry) compound; in { "2-octyldodecyl" = { section = "Substances"; text = { deu = { tex = "${compound.format "2-Octyl||dodecyl||gruppe"}"; }; }; description = { deu = '' eine Alkyl\-gruppe ''; }; data = { kind = "Chemical"; short = "2-OD"; struct = '' \cheme{\chemfig{-[:90]-[::60]-[::-60]-[::60]-[::-60]-[::60]-[::-60]-[::60]-[::-60]-[::60](-[::60]-[::60]-[::60]-[::-60]-[::60]-[::-60]-[::60]-[::-60])-[::-60]-[::60]R}}{} ''; }; }; acetyl = { section = "Substances"; text = { deu = { tex = "${compound.format "Acetyl||gruppe"}"; }; }; description = { deu = '' \ch{H3CCO}, eine Acyl\-gruppe ''; }; data = { kind = "Chemical"; short = "Ac"; struct = '' \cheme{\chemfig{R-[:30](=[::60]O)-[::-60]CH_3}}{} ''; }; }; benzyl = { section = "Substances"; text = { deu = { tex = "${compound.format "Benzyl||gruppe"}"; }; }; description = { deu = '' \ch{-CH2}, eine Aryl\-gruppe ''; }; data = { kind = "Chemical"; short = "Bzl"; struct = '' \cheme{\chemfig{R-[:30]-[::-60]*6(-=-=-=)}}{} ''; }; }; cyclopentadienyl = { section = "Substances"; text = { deu = { tex = "${compound.format "Cyclo||pentadienyl||gruppe"}"; }; }; description = { deu = '' vom ${compound.format "Cyclo|penta|di|en"}\-anion (\ch{C5H5-}) abgeleitet, eine Aryl\-gruppe ''; }; data = { kind = "Chemical"; short = "Cp"; struct = '' \cheme{\chemfig{R-[:30]**5(--(-[::126,0.88,,,,draw=none]\text{\ominus})---)}}{} ''; }; }; "cyclopentadienyl*" = { section = "Substances"; text = { deu = { tex = "${compound.format "Tetra|methyl||cyclo||penta|di|enyl||gruppe"}"; }; }; description = { deu = '' vom ${compound.format "Penta|methyl||cyclo|penta|di|en"}\-anion (\ch{C5(CH3)5-}) abgeleitet, eine Aryl\-gruppe ''; }; data = { kind = "Chemical"; short = "*"; }; }; dipp = { section = "Substances"; text = { deu = { tex = "${compound.format "Di|iso|propyl||phenyl||gruppe"}"; }; }; description = { deu = '' \ch{-()2}, eine Aryl\-gruppe ''; }; data = { kind = "Chemical"; short = "'dipp'"; }; }; ethyl = { section = "Substances"; text = { deu = { tex = "${compound.format "Ethyl||gruppe"}"; }; }; description = { deu = '' \ch{-CH2CH3}, eine Alkyl\-gruppe ''; }; data = { kind = "Chemical"; short = "Et"; struct = '' \cheme{\chemfig{R-[:30]-[:-30]CH_3}}{} ''; }; }; ferrocenyl = { section = "Substances"; text = { deu = { tex = "${compound.format "Ferrocenyl||gruppe"}"; }; }; description = { deu = '' von ${compound.format "Ferrocen"} (\ch{Fe(h5 -C5H5)2}) abgeleitet, eine Metallocyl\-gruppe ''; }; data = { kind = "Chemical"; short = "Fc"; struct = '' \cheme{\chemname{\chemfig{-[:-303.51,0.4476]-[::303.51,,,,]-[::303.51,0.4476]<[::251.67,0.7741]@{r5}{}>[::329.64,0.7741]-[::205.18,0.7472,,,draw=none]@{r1}{}-[::80,0.70]Fe-[::0,0.85]\ -[::0,0]@{r2}{}-[::85,0.7472,,,draw=none]<[::128.51,0.4476]@{r3}{}-[::56.49,,,,line width=2pt]@{r4}{}(-[::333.245]R)>[::56.49,0.4476]-[::108.33,0.7741]-[::30.36,0.7741]}}{gestaffelt}\chemname{\chemfig{<[:303.51-\rotate,0.4476]@{r15}{}-[:: 56.49,,,,line width=2pt]@{r16}{}>[:: 56.49,0.4476]-[::108.33,0.7741]-[::30.36,0.7741]-[::159.82,0.7472,,,draw=none]@{r11}{}-[::95,0.70]Fe-[:: 0,0.85]\ -[::0,0]@{r12}{}-[::85,0.7472,,,draw=none]<[::128.51,0.4476]@{r13}{}-[:: 56.49,,,,line width=2pt]@{r14}{}(-[::333.245]R)>[:: 56.49,0.4476]-[::108.33,0.7741]-[::30.36,0.7741]}}{ekliptisch}}{\draw[rotate=\rotate] (r1) ellipse (6pt and 2pt);\draw[rotate=\rotate] (r2) ellipse (6pt and 2pt);\draw[-,rotate=\rotate,line width=0.6pt] (r2)\fill[rotate=\rotate] (r3) ellipse (1.3pt and 1pt);\fill[rotate=\rotate] (r4) ellipse (1.3pt and 1pt);\fill[rotate=\rotate] (r5) ellipse (1pt and 1.3pt);\draw[rotate=\rotate] (r11) ellipse (6pt and 2pt);\draw[rotate=\rotate] (r12) ellipse (6pt and 2pt);\draw[-,rotate=\rotate,line width=0.6pt] (r12)\fill[rotate=\rotate] (r13) ellipse (1.3pt and 1pt);\fill[rotate=\rotate] (r14) ellipse (1.3pt and 1pt);\fill[rotate=\rotate] (r15) ellipse (1.3pt and 1pt);\fill[rotate=\rotate] (r16) ellipse (1.3pt and 1pt);} ''; }; }; fmoc = { section = "Substances"; text = { deu = { tex = "${compound.format "Fluorenyl||methoxy||carbonyl||gruppe"}"; }; }; description = { deu = '' \ch{???}, Schutz\-gruppe für \acrshort{forExample} ${compound.format "Amine"} ''; }; data = { kind = "Chemical"; short = "Fmoc"; }; }; isoPropyl = { section = "Substances"; text = { deu = { tex = "${compound.format "Iso|propyl||gruppe"}"; }; }; description = { deu = '' \ch{-CH(CH3)2}, eine Alkyl\-gruppe ''; }; data = { kind = "Chemical"; short = "^iPr"; struct = '' \cheme{\chemfig{R-[:30](-[:30]CH_3)-[:-30]CH_3}}{} ''; }; }; mesyl = { section = "Substances"; text = { deu = { tex = "${compound.format "Mesyl||gruppe"}"; }; }; description = { deu = '' \ch{-SO2CH3}, systematisch nach \acrshort{iupac}: ${compound.format "Methan||sulfonyl||gruppe"}, die Ester und Salze der ${compound.format "Methan||sulfonsäure"} (\ch{MsOH}) werden als ${compound.format "Mesylate"} bezeichnet, welche als Abgangs\-gruppe für nukleo\-phile Substitutions\-reaktionen durch Reaktion des ${compound.format "Säure\-chlorides"} mit einem ${compound.format "Alkohol"} gebildet werden kann ''; }; data = { kind = "Chemical"; short = "Ms"; struct = '' \cheme{\chemfig{R-[:30]-S(=[::75]O)(=[::45]O)[::-60]CH_3}}{} ''; }; }; methyl = { section = "Substances"; text = { deu = { tex = "${compound.format "Methyl||gruppe"}"; }; }; description = { deu = '' \ch{-CH3}, eine Alkyl\-gruppe ''; }; data = { kind = "Chemical"; short = "Me"; struct = '' \cheme{\chemfig{R-[:30]CH_3}}{} ''; }; }; naphthalenediimide = { section = "Substances"; text = { deu = { tex = "${compound.format "Naphthalen§-1,4,5,8-tetra|carboxyl§||di|imid"}"; }; }; description = { deu = '' von ${compound.format "Naphthalen"} abgeleite, tetrazyklische hetero\-aromatische Gruppe ''; }; data = { kind = "Chemical"; short = "NDI"; struct = '' \cheme{\chemfig{*6(-(*6(-(=O)-N(-R)-(=O)-))=(*6(-=-=(*6(-(=O)-N(-R)-(=O)-))-))-=-=)}}{} ''; }; }; phenyl = { section = "Substances"; text = { deu = { tex = "${compound.format "Phenyl||gruppe"}"; }; }; description = { deu = '' von ${compound.format "Benzen"} (\ch{C6H6}) abgeleitet, einem aromatischen ${compound.format "Kohlen||wasserstoff"}. ''; }; data = { kind = "Chemical"; short = "Ph"; struct = '' \cheme{\chemfig{R-[:30]*6(-=-=-=)}}{} ''; }; }; pyrenyl = { section = "Substances"; text = { deu = { tex = "${compound.format "Pyrenyl||gruppe"}"; }; }; description = { deu = '' von ${compound.format "Pyren"} (\ch{C16H10}) abgeleitet, einem poly\-zyklischen aromatischen ${compound.format "Kohlen||wasserstoff"}. ''; }; data = { kind = "Chemical"; short = "Py"; }; }; tosyl = { section = "Substances"; text = { deu = { tex = "${compound.format "Tosyl||gruppe"}"; }; }; description = { deu = '' \ch{-SO2}, systematisch nach \acrshort{iupac}: ${compound.format "p-Toluen||sulfonyl||gruppe"}, die Ester und Salze der ${compound.format "p-Toluen||sulfonsäure"} (\ch{TsOH}) werden als ${compound.format "Tosylate"} bezeichnet, welche als Abgangs\-gruppe für nukleo\-phile Substitutions\-reaktionen durch Reaktion des ${compound.format "Säure\-chlorides"} mit einem ${compound.format "Alkohol"} gebildet werden kann ''; }; data = { kind = "Chemical"; short = "Ts"; }; }; triflyl = { section = "Substances"; text = { deu = { tex = "${compound.format "Triflyl||gruppe"}"; }; }; description = { deu = '' \ch{-SO2CF3}, systematisch nach \acrshort{iupac}: ${compound.format "Tri|fluor||methan||sulfonyl||gruppe"}, die Ester und Salze der ${compound.format "Tri|fluor||methan||sulfonsäure"} (\ch{TfOH}) werden als ${compound.format "Triflate"} bezeichnet, welche als Abgangs\-gruppe für nukleo\-phile Substitutions\-reaktionen durch Reaktion des ${compound.format "Säure\-chlorides"} mit einem ${compound.format "Alkohol"} gebildet werden kann ''; }; data = { kind = "Chemical"; short = "Tf"; }; }; trimethylsilyl = { section = "Substances"; text = { deu = { tex = "${compound.format "Tri|methyl||silyl||gruppe"}"; }; }; description = { deu = '' \ch{-Si(CH3)3} ''; }; data = { kind = "Chemical"; short = "TMS"; struct = '' \cheme{\chemfig{R-Si(-[::-120]H_3C)(-[::120]H_3C)-[::0]CH_3}}{} ''; }; }; }